@Daniel-Wright The way that I learnt Python was by reading this book: http://learnpythonthehardway.org. It's an intimidating title, but it's not as hard as you might think, and it does a great job of building up some good habits when you are writing code in Python.
Im currently looking into audio support, with the server software I use, there is a shairport plugin. So Apple devices would share to the server software which in turn passes it onto the client (wifi speaker) devices.
If I get the squeezeslave software to work, if you have a similar server software setup (if you have multiple speakers Id assume so) then there shouldnt be a problem.
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